The captain sat out the 2-0 win over Italy in Manchester on Friday because of a muscle injury but has been cleared to lead his country out in Madrid.
"Messi has a revolver put to his head called the World Cup", he said.
Although fellow Argentine forward Paolo Dybala had previously claimed that Messi's dominance of the final third made it tough to play alongside him in the national team, the "Little Master" says the comment was not taken as an insult.
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"We are not thinking too much about who we will be playing".
"If there was any risk (in his condition), Leo would have said".
Messi will face a Spain that includes his Barcelona teammates Andres Iniesta, Gerard Pique, and Jordi Alba at Atletico Madrid's Wanda Metropolitano Stadium. Dybala has to be pleased as he might participate in this summer's World Cup with Argentina after all. It's always special to play against him, " De Gea added.
Even without Messi's injured Barca team-mate Sergio Busquets, Spain produced another impressive display of controlled football when they drew 1-1 away to Germany on Friday night. Moving from the right, when we cut inside, the whole pitch is in front of us.
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National teams are using the Adidas Telstar 18 for the first time during the current round of internationals and the lack of grip and excessive movement through the air has been criticised.
"If I play just one game a week, I struggle to get started.
To see what will make us work like a team", admitting that while Argentina still had work to do to decide their strongest side, "Spain have their side already consolidated. if they are not the best side in the world, they are among the best".
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